Beilstein J. Org. Chem.2016,12, 2588–2601, doi:10.3762/bjoc.12.254
; recombinant E. coli uridine, thymidine and purine nucleoside phosphorylases; substrate properties; 4(2)-thioxo- and6(5)-aza-uaciland -thymine; Introduction
Nucleosides of 4- and 2-thioxopyrimidines and 6-azapyrimidines attract much attention from the time of pioneering works in the early 1950s on the
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Graphical Abstract
Scheme 1:
Enzymatic synthesis of 2-deoxy-β-D-ribofuranosides 1b–5b of the heterocyclic bases 1a–5a. Regents a...